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Presents the developments in characterization and application of supported metals in heterogeneous catalysis. This book includes coverage of the traditional aspects of heterogeneous catalysis such as preparation, characterization and use in well-established technologies such as Naphtha reforming.
Covers fundamental and applied aspects of the advances in ceria-based materials with a special focus on structural, redox and catalytic features of nano-engineered systems.
Research on designing catalytic systems has been one of the most important fields in modern organic chemistry, and one reason for this is the predominant contribution of catalysis to the concepts of atom economy and green chemistry in the 21st century. This book presents the major advances in homogeneous catalysis.
Offers a comprehensive treatment of combinatorial development of heterogeneous catalysts. The book describes evolutionary optimization in a broader context of methods of searching for optimal catalytic materials, including statistical design of experiments, as well as presents neural networks in a broader context of data analysis.
Syngas is a mixture of hydrogen and carbon oxides which can be made from hydrocarbons, coal and biomass. It is an important intermediate in the chemical industry for manufacture of ammonia, methanol and other petrochemicals as well as hydrogen for refineries and fuel cells. This book provides a general overview of syngas technologies.
Aims to review the application of isotopic methods to the field of heterogeneous catalysis. This work includes application of specific isotopes, as well as isotopic techniques - determination of surface mobility, steady state transient isotope kinetic analysis, and positron emission profiling.
Describes the properties of gold, the methods for preparing gold catalysts and ways to characterise and use them effectively in reactions. This book discusses the reaction mechanisms and reasons for the high activities, and considers the applications for gold catalysis.
Heterocyclic chemistry constitutes the largest branch of chemistry, covering almost two-thirds of literature in the field.
Gives an overview of the technologies and economics in the production of olefins in the petrochemical industries. This compendium highlights the options and costs for producing olefins using different technologies and different feedstocks at a time when the cost of carbon dioxide emissions are set to be included in the production cost.
In chemical processes, the progressive deactivation of solid catalysts is a major economic concern and mastering their stability has become as essential as controlling their activity and selectivity. This book covers in a comprehensive way both the fundamental and applied aspects of solid catalyst deactivation.
A review of advances in the field of catalysis by ceria and related materials, focusing on fundamental and applied issues. It explores the structural and chemical properties of ceria and related materials, and evaluates the role of ceria in catalytic processes such as fluid catalytic cracking.
Chiral titanium complexes are low-cost, low-toxicity and high-efficiency catalysts. Impressive progress on enantioselective titanium-catalysed transformations has been achieved in the past seven years, with exciting new discoveries ranging from basic reactions to novel methodologies. Despite this, the field has not been substantially reviewed since 2008.This book contains up to date research and covers all types of enantioselective transformations using chiral titanium catalysts. It illustrates the economic, health, and environmental benefits of chiral titanium catalysts, showing the types of highly enantioselective reactions that they are able to induce are unlimited.Work presented here is aimed at researchers in organic and catalytic chemistry, and has been carefully curated to encourage future research possibilities.
This book documents Professor Jacques Simonet's contribution to building new electrode materials and their related catalytic reactions. Research includes synthesis of new alloys of palladium, discovery of new composite electrodes (including gold- and silver-graphene) and the creation of new materials through judicious cathodic or anodic doping. Additionally, studies demonstrate the malleability and reactivity of previously unused precious and semi-precious metals for the creation of 2D and 3D catalytic materials. Studies key to innovative research show how transition metals may reversibly cathodically insert small size electro-active molecules such as CO2 and O2, and be applied to methods of depollution brought by carbon and nitrogen oxides.Written for practical use, Simonet has provided both theory and tools needed for those aiming to recreate and develop his experiments in electrochemical catalysis and surface modifications. This full publication of research gives graduate and post-graduate students of chemistry, electrochemistry and catalysis an in-depth insight into key historical and modern developments in the field.
The demand for hydroprocessing catalysts has shown an increasing trend, because of their applications in refining of petroleum and biofuels, in order to comply with strict environmental regulations controlling emissions from transportation vehicles.Transport fuel is dominated by fossil fuels with carbon emission intensive production methods. If we are to move away from these sources, the alternative is to produce liquid fuels from agricultural stocks - crops, crop waste, forestry waste or algae. Converting these feedstocks into high quality fuels is a considerable challenge.By describing the current status in processing agricultural feedstock into high quality liquid transport fuels, the authors set out the means to develop better chemistry and catalysis for the necessary conversion processes. This book offers an intriguing insight into the mechanisms and protocols involved in new hydroprocessing catalysts and processes, and covers the methods for upgrading these liquids to modern transport vehicles suitable for operation in modern gasoline and diesel engines.It provides an introduction to the mechanism of hydroprocessing reactions, application of different metals in hydroprocessing, the effect of catalyst supports, applications in refining new feedstock, renewable fuels standards, the management of spent hydroprocessing catalysts, and hydrogen production.Hydroprocessing Catalysts and Processes will prove useful for both researchers in academe and industry concerned with future fuels development and treatment to produce current and future liquid transport fuels.
The use of organocatalysts able to photocatalyze an organic reaction is a rapidly growing field. These photocatalyzed transformations are more environmentally sustainable with respect to the use of expensive/toxic metal-based (photo)catalysts.Based on the authors' extensive experience in photogenerated intermediates, this book presents an overview on photocatalyzed organic processes having a synthetic significance, where an organic molecule functions as the photocatalyst.
Iron Catalysis: Design and Applications is an exciting new book that takes readers inside the world of iron catalysis guided by international catalysis expert, Dr Jose M Palomo.
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